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Chemical Compound Review: 

Biisopropenyl     2,3-dimethylbuta-1,3-diene

Synonyms: Diisopropenyl, NSC-8656, AG-F-73824, NSC8656, LTBB002745, ...
 
 
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High impact information on NSC8656

  • Fluorescence spectra, singlet-state lifetimes, and Stern-Volmer quenching of fluorescence with 2,3-dimethyl-1,3-butadiene indicated that the excited singlet states of these three isomers were spectroscopic minima and that the excited singlet state was the reactive one for 3 in acetonitrile [1].
  • Formation of [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne [2].

References

  1. Phototransposition reactions of arylboronate esters in acetonitrile and 2,2,2-trifluoroethanol. Cameron, K.S., Pincock, A.L., Pincock, J.A., Thompson, A. J. Org. Chem. (2004) [Pubmed]
  2. Formation of [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne. Stender, M., Phillips, A.D., Power, P.P. Chem. Commun. (Camb.) (2002) [Pubmed]
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