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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

Craig A. Grapperhaus

Department of Chemistry

University of Louisville


KY 40292



Name/email consistency: high



  • Department of Chemistry, University of Louisville, Louisville, KY 40292, USA. 2002 - 2013


  1. Bioinspired catalytic nitrile hydration by dithiolato, sulfinato/thiolato, and sulfenato/sulfinato ruthenium complexes. Kumar, D., Masitas, C.A., Nguyen, T.N., Grapperhaus, C.A. Chem. Commun. (Camb.) (2013) [Pubmed]
  2. Kinetic study of nickel-thiolate oxygenation by hydrogen peroxide. Implications for nickel-containing superoxide dismutase. Herdt, D.R., Grapperhaus, C.A. Dalton. Trans (2012) [Pubmed]
  3. Carbon-sulfur bond formation via alkene addition to an oxidized ruthenium thiolate. Grapperhaus, C.A., Venna, K.B., Mashuta, M.S. Inorg. Chem (2007) [Pubmed]
  4. Singlet diradical character of an oxidized ruthenium trithiolate: electronic structure and reactivity. Grapperhaus, C.A., Kozlowski, P.M., Kumar, D., Frye, H.N., Venna, K.B., Poturovic, S. Angew. Chem. Int. Ed. Engl. (2007) [Pubmed]
  5. Oxygenation of a ruthenium(II) thiolate to a ruthenium(II) sulfinate proceeds via ruthenium(III). Grapperhaus, C.A., Poturovic, S., Mashuta, M.S. Inorg. Chem (2005) [Pubmed]
  6. Synthesis and oxygenation of a nickel(II) and zinc(II) dithiolate: an experimental and theoretical comparison. Grapperhaus, C.A., Mullins, C.S., Kozlowski, P.M., Mashuta, M.S. Inorg. Chem (2004) [Pubmed]
  7. Electrochemical investigations of the [tris(2-(diphenylphosphino)thiaphenolato)ruthenate(II)] monoanion reveal metal- and ligand-centered events: radical, reactivity, and rate. Grapperhaus, C.A., Poturovic, S. Inorg. Chem (2004) [Pubmed]
  8. Synthesis and characterization of N2S3X-Fe models of iron-containing nitrile hydratase. Grapperhaus, C.A., Li, M., Patra, A.K., Poturovic, S., Kozlowski, P.M., Zgierski, M.Z., Mashuta, M.S. Inorg. Chem (2003) [Pubmed]
  9. First [Fe-NO](6) complex with an N(2)S(3)Fe-NO core as a model of NO-inactivated iron-containing nitrile hydratase. Are thiolates and thioethers equivalent donors in low-spin iron complexes?. Grapperhaus, C.A., Patra, A.K., Mashuta, M.S. Inorg. Chem (2002) [Pubmed]
  10. Dichloromethane alkylates a trithiolato-ruthenium complex to yield a methylene-bridged thioether core. Synthesis and structural comparison to the thiolato-ruthenium precursor. Grapperhaus, C.A., Poturovic, S., Mashuta, M.S. Inorg. Chem (2002) [Pubmed]
  11. 1,5-Bis(benzothiazolyl)-3-thiapentane and its asymmetric dinuclear Ag(I) complex with three distinct intermolecular-stacking interactions. Grapperhaus, C.A., Li, M., Mashuta, M.S. Chem. Commun. (Camb.) (2002) [Pubmed]
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