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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Chemical Compound Review: 

Triethylsilan     triethylsilane

Synonyms: ACMC-209mw9, ANW-33943, AC1L1YQI, CTK3J1347, KSC491G4P, ...
 
 
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High impact information on triethylsilane

  • Removal of the phenylfluorenyl group was achieved with up to 3% TFA in dichloromethane in the presence of triethylsilane at 0 degrees C. These protecting-group techniques were successfully applied in the synthesis of differently lipidated H-Ras peptides [1].
  • The key reaction involves the tandem deoxygenation and cyclization of a triarylmethanol using a combination of triethylsilane and trifluoroacetic acid [2].
  • [reaction: see text] A triphenylmethyl (trityl) ether was reductively and instantaneously cleaved by triethylsilane in the presence of a catalytic amount of TES- (or TMS)-triflate [3].

References

  1. Acid-labile protecting groups for the synthesis of lipidated peptides. Kadereit, D., Deck, P., Heinemann, I., Waldmann, H. Chemistry (Weinheim an der Bergstrasse, Germany) (2001) [Pubmed]
  2. Concise total syntheses of variolin B and deoxyvariolin B. Anderson, R.J., Hill, J.B., Morris, J.C. J. Org. Chem. (2005) [Pubmed]
  3. Triethyl- (or trimethyl-)silyl triflate-catalyzed reductive cleavage of triphenylmethyl (trityl) ethers with triethylsilane. Imagawa, H., Tsuchihashi, T., Singh, R.K., Yamamoto, H., Sugihara, T., Nishizawa, M. Org. Lett. (2003) [Pubmed]
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