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Chemical Compound Review: 

Fulvene     5-methylidenecyclopenta-1,3- diene

Synonyms: fulveno, Fulven, AGN-PC-0D76R4, AG-F-66554, CHEBI:51999, ...
 
 
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Disease relevance of fulvene

  • The scheme employs the equivalence of torsion and interchange of equivalent H-atoms in a class of molecules of which fulvene is a simple example [1].
 

High impact information on fulvene

  • The conversion of 3 to 8 proceeds by the initial retro-Diels-Alder reaction followed by isomerization of the fulvene to 1-isopropenyl-1,3-cyclopentadiene that then reacts with BTF to give the alternative Diels-Alder product as a single regioisomer [2].

References

  1. Toward separation of nuclear spin isomers with coherent light. Deeb, O., Leibscher, M., Manz, J., von Muellern, W., Seideman, T. Chemphyschem : a European journal of chemical physics and physical chemistry (2007) [Pubmed]
  2. Reaction of 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene with 6,6-dimethylfulvene: cycloadditions and a rearrangement. Howard, M.H., Alexander, V., Marshall, W.J., Roe, D.C., Zheng, Y.J. J. Org. Chem. (2003) [Pubmed]
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