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Chemical Compound Review: 

cycloheptane     cycloheptane

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High impact information on cycloheptane

  • This methodology is based on the intramolecular Friedel-Crafts acylation of the corresponding 12-desoxylabdanoic-like acids 27, for the construction of the cycloheptane ring which is characteristic of the hispananes [1].
  • The conformers of cycloheptane through cyclodecane have been examined at the B3LYP/6-311+G* and MP2/6-311+G* theoretical levels, with some additional calculations at the CCD/6-311+G* and CCSD(T)/6-311++G** levels [2].

References

  1. Diversity oriented synthesis of hispanane-like terpene derivatives from (R)-(+)-sclareolide. de la Torre, M.C., García, I., Sierra, M.A. Chemistry (Weinheim an der Bergstrasse, Germany) (2005) [Pubmed]
  2. The C7-C10 cycloalkanes revisited. Wiberg, K.B. J. Org. Chem. (2003) [Pubmed]
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