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Chemical Compound Review

AC-677     palladium(+2) cation diethanoate

Synonyms: AG-F-14113, ACMC-209i2m, ANW-27692, AK-98692, LS-12687, ...
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Psychiatry related information on acetic acid

  • [reaction: see text] Room-temperature reduction of aromatic nitro groups to amines can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min) using a combination of palladium(II) acetate, aqueous potassium fluoride, and polymethylhydrosiloxane (PMHS) [1].
 

High impact information on acetic acid

  • Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim]PF6, was highly efficient in the promotion of the Mizoroki-Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h(-1)), respectively [2].
  • An interfacial polymerisation approach is adopted to encapsulate palladium(II) acetate and palladium nanoparticles in polyurea microcapsules for use in catalysis [3].
 

Analytical, diagnostic and therapeutic context of acetic acid

  • Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography [4].

References

  1. Pd-catalyzed silicon hydride reductions of aromatic and aliphatic nitro groups. Rahaim, R.J., Maleczka, R.E. Org. Lett. (2005) [Pubmed]
  2. Sustainable Mizoroki-Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid. Hagiwara, H., Sugawara, Y., Hoshi, T., Suzuki, T. Chem. Commun. (Camb.) (2005) [Pubmed]
  3. Encapsulation of palladium in polyurea microcapsules. Ramarao, C., Ley, S.V., Smith, S.C., Shirley, I.M., DeAlmeida, N. Chem. Commun. (Camb.) (2002) [Pubmed]
  4. Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins. Graham, S.R., Ferrence, G.M., Lash, T.D. Chem. Commun. (Camb.) (2002) [Pubmed]
 
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