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Chemical Compound Review:

Ethenylsilane ethenylsilane

Synonyms: CTK2H9421, AC1L31X2

Cunningham, J.L. et al., Barbero, A. et al., Guo, D.J. et al., Kuroda, S. et al.

Barbero, Blanco, Pulido,

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High impact information on ethenylsilane

Hydrolysis of 8 or 9 afforded vinylsilane 13 or allylsilane 16 [1].
The different reactivity of these two units has been employed in the intramolecular allylsilane-terminated cyclization of these adducts, where the vinylsilane moiety remains unchanged [2].
Photolysis of 1 with vinyltrimethylsilane ultimately yields three isomeric products of [CH2(eta5-C5H4)2][Rh(CH2=CHSiMe3)2]2, 3a, 3b and 3c which are differentiated by the relative orientations of the vinylsilane [3].

Analytical, diagnostic and therapeutic context of ethenylsilane

Diffusion of hydrosilanes from the control layer to the vinylsilane-rich flow membrane during the fabrication of microfluidic chips [4].

References

Formation of silazirconacyclopentenes from zirconium-silene complex and alkynes and their reactivities. Kuroda, S., Dekura, F., Sato, Y., Mori, M. J. Am. Chem. Soc. (2001) [Pubmed]
Silylcuprates from allene and their reaction with alpha,beta-unsaturatedd nitriles and imines. Synthesis of silylated oxo compounds leading to cyclopentane and cycloheptane ring formation. Barbero, A., Blanco, Y., Pulido, F.J. J. Org. Chem. (2005) [Pubmed]
Photochemical reactions of [CH2(eta5-C5H4)2][Rh(C2H4)2]2 with silanes: evidence for Si-C and C-H activation pathways. Cunningham, J.L., Duckett, S.B. Dalton transactions (Cambridge, England : 2003) (2005) [Pubmed]
Diffusion of hydrosilanes from the control layer to the vinylsilane-rich flow membrane during the fabrication of microfluidic chips. Guo, D.J., Xiao, S.J., Liu, H.B., Chao, J., Xia, B., Wang, J., Pei, J., Pan, Y., Gu, Z.Z., You, X.Z. Langmuir : the ACS journal of surfaces and colloids. (2005) [Pubmed]

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