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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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A general synthetic method for the formation of substituted 5-aminotetrazoles from thioureas: a strategy for diversity amplification.

A general method for the synthesis of 5-aminotetrazoles is outlined using the mercury(II)-promoted attack of azide anion on a thiourea. The reaction proceeds through a guanyl azide intermediate, which undergoes electrocyclization to the tetrazole. The method is high yielding and provides access to mono-, di-, and trisubstituted 5-aminotetrazoles, targets of potential interest for combinatorial library development.[1]

References

  1. A general synthetic method for the formation of substituted 5-aminotetrazoles from thioureas: a strategy for diversity amplification. Batey, R.A., Powell, D.A. Org. Lett. (2000) [Pubmed]
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