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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 
 
 

Studies on the potentiometric thallium(III)-selective carbon paste electrode and its possible applications.

Construction, performance characteristics and applications of a carbon paste thallium(III) ion-selective electrode are described. The electrode, which is based on ion-associate compounds formed between cetylpyridinium and chlorothallate(III) complexes dissolved in tricresyl phosphate as pasting liquid, showed near-Nernstian response over the concentration range of 5.8 x 10(-6) - 2.9 x 10(-3) mol/L. Potentiometric titrations of thallium(III) with cetylpyridinium chloride were affected by higher concentrations of excess halides, probably due to the formation of higher halogenothallates.[1]

References

  1. Studies on the potentiometric thallium(III)-selective carbon paste electrode and its possible applications. Vytras, K., Khaled, E., Jezková, J., Hassan, H.N., Barsoum, B.N. Fresenius' journal of analytical chemistry. (2000) [Pubmed]
 
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