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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 
 
 

Experimental determination and prediction of the gas-liquid n-hexadecane partition coefficients.

Experimental methods based on gas-phase chromatography were tested with a view to determine the gas-liquid n-hexadecane partition coefficients, log L16 of non-volatile compounds at 298.2 K. It was demonstrated that reliable values of log L16 of compounds more volatile than n-docosane can be obtained using either capillary, or packed columns. The main limitation of both methods is the column stability at high temperatures. Here we propose a new method based on the temperature gradient mode, to obtain log L16 of high-boiling compounds. A group contribution model is also presented in view to predicting log L16 values of non-volatile compounds.[1]

References

  1. Experimental determination and prediction of the gas-liquid n-hexadecane partition coefficients. Mutelet, F., Rogalski, M. Journal of chromatography. A. (2001) [Pubmed]
 
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