High-performance nitrate-selective electrodes containing immobilized amino acid betaines as sensors.
Ten nitrate-selective electrodes based upon rubbery membranes containing various betaine salts as sensors covalently bound to a cross-linked polystyrene-block-polybutadiene-block-polystyrene ( SBS) polymer have been produced. The membranes were robust, highly selective, and effective over a pH range of 2-8. The best nitrate-selective electrode fabricated contained 10% m/m dicumyl peroxide, 40% 2-nitrophenyloctyl ether, 6.5% triallyl leucine betaine chloride and 43.5% SBS. The characteristics of this electrode were a linear Nernstian range of 1 x 10(-1) to 5 x 10(-6) mol dm(-3) NO3-, a limit of detection of 3.4 x 10(-7) mol dm(-3) NO3-, and a selectivity coefficient for nitrate against chloride, K(NO3-,Cl-)pot, of 3.4 x 10(-3). These figures represent a significant improvement on current commercial nitrate sensors. Response times were 1 min or less; stability of response and electrode lifetime in continuous use was also very satisfactory.[1]References
- High-performance nitrate-selective electrodes containing immobilized amino acid betaines as sensors. Le Goff, T., Braven, J., Ebdon, L., Scholefield, D. Anal. Chem. (2002) [Pubmed]
Annotations and hyperlinks in this abstract are from individual authors of WikiGenes or automatically generated by the WikiGenes Data Mining Engine. The abstract is from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.About WikiGenesOpen Access LicencePrivacy PolicyTerms of Useapsburg
