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Miranda, M.A. et al.

Miranda, Izquierdo,

Chemical and transient spectroscopic evidence for C2-C3 cleavage of 2,3-diaryloxetane radical cations.

Electron transfer cycloreversion of the methoxy substituted oxetane 1b results in the production of trans-anethole and benzaldehyde through C2-C3 bond cleavage. trans-Anethole radical cation has been detected as transient intermediate by laser flash photolysis.[1]

References

Chemical and transient spectroscopic evidence for C2-C3 cleavage of 2,3-diaryloxetane radical cations. Miranda, M.A., Izquierdo, M.A. Chem. Commun. (Camb.) (2003) [Pubmed]

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