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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system.

The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.[1]

References

  1. A rapid and effective synthesis of propylene carbonate using a supercritical CO2-ionic liquid system. Kawanami, H., Sasaki, A., Matsui, K., Ikushima, Y. Chem. Commun. (Camb.) (2003) [Pubmed]
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