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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Platinum(II)-bis(9-methyladenine) complexes; N1-->N6 migration of Pt(II)vs deamination of coordinated methyladenine.

Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N1) complex of cis-Pt(II)(NH(3))(2) in basic solution, whereafter deamination of the 9-methyladenine still coordinated at N-1 competes with a second migration step.[1]

References

  1. Platinum(II)-bis(9-methyladenine) complexes; N1-->N6 migration of Pt(II)vs deamination of coordinated methyladenine. Klika, K.D., Arpalahti, J. Chem. Commun. (Camb.) (2004) [Pubmed]
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