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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Self-assembly, binding, and dynamic properties of heterodimeric porphyrin macrocycles.

A series of heterodimeric tetralactam macrocycles have been self-assembled using two kinetically labile zinc porphyrin-pyridine interactions. The stability constants have been determined by UV-vis titrations in CHCl(3). The stability constants depend on the degree of preorganization of the linker units connecting the interacting groups. The ability of the self-assembled macrocycles to bind a terephthalamide guest was also investigated. One of the macrocycles was used for the construction of a [2]rotaxane. The dynamic properties of this system provide insight into the exchange mechanisms that operate in complex noncovalent assemblies.[1]

References

  1. Self-assembly, binding, and dynamic properties of heterodimeric porphyrin macrocycles. Ballester, P., Costa, A., Deyà, P.M., Frontera, A., Gomila, R.M., Oliva, A.I., Sanders, J.K., Hunter, C.A. J. Org. Chem. (2005) [Pubmed]
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