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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 
 
 

Anion-pi interactions in cyanuric acids: a combined crystallographic and computational study.

Several structures of pi complexes of isocyanuric acid and of several thio derivatives with anions have been computed by using high level ab initio calculations. The nature of the complexes has been studied by means of the method of molecular interaction potential with polarization (MIPp) and Bader's theory of atoms-in-molecules. These molecules form favorable complexes with anions and can be used as binding units for building receptors for the molecular recognition of anions. In several cases, the anion-pi interaction has been demonstrated experimentally by means of X-ray crystallography.[1]

References

  1. Anion-pi interactions in cyanuric acids: a combined crystallographic and computational study. Frontera, A., Saczewski, F., Gdaniec, M., Dziemidowicz-Borys, E., Kurland, A., Deyà, P.M., Quiñonero, D., Garau, C. Chemistry (Weinheim an der Bergstrasse, Germany) (2005) [Pubmed]
 
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