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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates.

[reaction: see text] Benzene-fused cyclic sulfamates are prepared from ortho-substituted phenolic starting materials through selective C-H amination or olefin aziridination. These unique heterocycles will engage in Ni-catalyzed cross-coupling reactions with aryl- and alkyl-Grignard reagents. Application of modern tools for C-N and C-C bond formation thus makes readily available functional amine derivatives and augments the possible uses for C-H amination in synthesis.[1]

References

  1. Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates. Wehn, P.M., Du Bois, J. Org. Lett. (2005) [Pubmed]
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