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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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pH-dependent kinetics of MgCl(2) adsorption under a fatty-acid Langmuir film.

The effect of subphase pH (5.5 and 10.5) on the structure of behenic-acid monolayers was investigated during Mg(2+) adsorption by means of Grazing Incidence X-ray Diffraction (GIXD) and Brewster Angle Microscopy (BAM). The final phase corresponding to an ion superlattice commensurate to the behenic-acid cell is pH-independent. In contrast, the sequence of phases evidenced from the initial L(2)-phase to this final state presents at pH 10.5 an additional stage associated to a film condensation toward the L' (2)-phase. The structures of the intermediate states preceding the superstructure nucleation are slightly different, both with a short-range fatty-acid order. Finally, a laser light effect that could result from visible light absorption by the inorganic complexes is evidenced in the final state as well as in the intermediate phases.[1]

References

  1. pH-dependent kinetics of MgCl(2) adsorption under a fatty-acid Langmuir film. Pignat, J., Cantin, S., Liu, R.C., Goldmann, M., Fontaine, P., Daillant, J., Perrot, F. The European physical journal. E, Soft matter. (2006) [Pubmed]
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