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Enders, D. et al.

Dieter Enders, Thanh Vinh Nguyen,

Chiral quaternary phosphonium salts: a new class of organocatalysts.

Phase-transfer catalysis has widely been used as a prime synthetic tool for both laboratory and industrial processes. During the last twenty years, asymmetric phase-transfer catalysis using chiral organocatalysts has attracted widespread interest. However, the scope of chiral phase-transfer catalysis has been limited mostly to the quaternary ammonium salts. As an emerging area, the recent developments in the application of quaternary phosphonium salts as chiral phase-transfer catalysts are discussed in this article.[1]

References

Chiral quaternary phosphonium salts: a new class of organocatalysts. Enders, D., Nguyen, T.V. Org. Biomol. Chem. (2012) [Pubmed]

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