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Chemical Compound Review

DIPEA     N-ethyl-N-propan-2-yl-propan- 2-amine

Synonyms: diea, AmbotzSOL-003, PubChem12842, Huenigs base, ACMC-1BELW, ...
 
 
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High impact information on Diisopropylethylamine

 

Biological context of Diisopropylethylamine

 

Gene context of Diisopropylethylamine

  • Here, we report total synthesis of human alpha-defensins 4, 5, and 6, also known as HNP4, HD5, and HD6, using the optimized N,N-diisopropylethylamine (DIEA) in situ neutralization/2-(1 H-benzotriazolyl)-1,1,3,3-tetramethyluroniumhexafluorophosphate (HBTU) activation protocol for solid-phase Boc chemistry [7].
  • A total synthesis of [Ala15]-GRF(1-29)-NH2 was also carried out using the BOP procedure (single couplings and 3 equiv. BOP and Boc-amino acids and 5.3 equiv. diisopropylethylamine in DMF for each cycle) [8].

References

  1. Synthesis of stable dodecaalkoxy derivatives of hypercloso-B12H12. Farha, O.K., Julius, R.L., Lee, M.W., Huertas, R.E., Knobler, C.B., Hawthorne, M.F. J. Am. Chem. Soc. (2005) [Pubmed]
  2. Solid-phase synthesis and spectral properties of 2-alkylthio-6H-pyrano[2,3-f]benzimidazole-6-ones: a combinatorial approach for 2-alkylthioimidazocoumarins. Song, A., Zhang, J., Lebrilla, C.B., Lam, K.S. Journal of combinatorial chemistry. (2004) [Pubmed]
  3. Affinity enhancement bivalent morpholino for pretargeting: initial evidence by surface plasmon resonance. He, J., Liu, G., Vanderheyden, J.L., Dou, S., Mary, R., Hnatowich, D.J. Bioconjug. Chem. (2005) [Pubmed]
  4. Catalytic, asymmetric preparation of ketene dimers from acid chlorides. Calter, M.A., Orr, R.K., Song, W. Org. Lett. (2003) [Pubmed]
  5. Derivatization procedures to facilitate de novo sequencing of lysine-terminated tryptic peptides using postsource decay matrix-assisted laser desorption/ionization mass spectrometry. Keough, T., Lacey, M.P., Youngquist, R.S. Rapid Commun. Mass Spectrom. (2000) [Pubmed]
  6. Fmoc-amino acid chlorides in solid phase synthesis of opioid peptides. Sivanandaiah, K.M., Babu, V.V., Renukeshwar, C. Int. J. Pept. Protein Res. (1992) [Pubmed]
  7. Synthesis and characterization of human alpha-defensins 4-6. Wu, Z., Ericksen, B., Tucker, K., Lubkowski, J., Lu, W. J. Pept. Res. (2004) [Pubmed]
  8. Applications of BOP reagent in solid phase synthesis. Advantages of BOP reagent for difficult couplings exemplified by a synthesis of [Ala 15]-GRF(1-29)-NH2. Fournier, A., Wang, C.T., Felix, A.M. Int. J. Pept. Protein Res. (1988) [Pubmed]
 
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