Koichi Mikami
Department of Chemical Technology
Tokyo Institute of Technology
Japan
Name/email consistency: high
- Metal enolates of alpha-CF3 ketones: theoretical guideline, direct generation, and synthetic use. Mikami, K., Itoh, Y. Chem. Rec (2006)
- "Achiral" benzophenone ligand for highly enantioselective Ru catalysts in ketone hydrogenation. Mikami, K., Wakabayashi, K., Aikawa, K. Org. Lett. (2006)
- Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation. Mikami, K., Wakabayashi, K., Yusa, Y., Aikawa, K. Chem. Commun. (Camb.) (2006)
- Radical trifluoromethylation of ketone silyl enol ethers by activation with dialkylzinc. Mikami, K., Tomita, Y., Ichikawa, Y., Amikura, K., Itoh, Y. Org. Lett. (2006)
- Enantiodiscrimination and enantiocontrol of neutral and cationic PtII complexes bearing the tropos biphep ligand: application to asymmetric lewis acid catalysis. Mikami, K., Kakuno, H., Aikawa, K. Angew. Chem. Int. Ed. Engl. (2005)
- Tropos or atropos nature of rhodium complexes bearing a tetrakis(phosphanyl)terphenyl ligand: highly enantioselective catalysis of ene-type cyclization. Mikami, K., Kataoka, S., Aikawa, K. Org. Lett. (2005)
- Fluorinated carbonyl and olefinic compounds: basic character and asymmetric catalytic reactions. Mikami, K., Itoh, Y., Yamanaka, M. Chem. Rev. (2004)
- Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex. Mikami, K., Yusa, Y., Hatano, M., Wakabayashi, K., Aikawa, K. Chem. Commun. (Camb.) (2004)
- Palladium-catalyzed carbocyclization of 1,6-enynes leading to six-membered rings or oxidized five-membered trifluoroacetates. Mikami, K., Hatano, M. Proc. Natl. Acad. Sci. U.S.A. (2004)
- A highly efficient asymmetric Suzuki-Miyaura coupling reaction catalyzed by cationic chiral palladium(ii) complexes. Mikami, K., Miyamoto, T., Hatano, M. Chem. Commun. (Camb.) (2004)
- Racemic but tropos (chirally flexible) BIPHEP ligands for Rh(I)-complexes: highly enantioselective ene-type cyclization of 1,6-enynes. Mikami, K., Kataoka, S., Yusa, Y., Aikawa, K. Org. Lett. (2004)
- Molecular design of DABNTf as a highly efficient resolving reagent for racemic Pd complex with Tropos biphenylphosphine (BIPHEP) ligand: circular dichroism (CD) spectra of enantiopure BIPHEP-Pd complex. Mikami, K., Yusa, Y., Aikawa, K., Hatano, M. Chirality (2003)
- (2,5)-Ene cyclization catalyzed by mesoporous solid acids: isotope labeling study and ab initio calculation for continuum from concerted to stepwise ene mechanism. Mikami, K., Ohmura, H., Yamanaka, M. J. Org. Chem. (2003)
- Resolution of Pd catalyst with tropos biphenylphosphine (BIPHEP) ligand by DM-DABN: asymmetric catalysis by an enantiopure BIPHEP-Pd complex. Mikami, K., Aikawa, K., Yusa, Y., Hatano, M. Org. Lett. (2002)
- Asymmetric activation of the Pd catalyst bearing the tropos biphenylphosphine (BIPHEP) ligand with the chiral diaminobinaphthyl (DABN) activator. Mikami, K., Aikawa, K., Yusa, Y. Org. Lett. (2002)
- Dynamic asymmetric catalysis by diphenylphosphinoferrocene (DPPF)-nickel complexes through control of axial chirality by chiral diamines. Mikami, K., Aikawa, K. Org. Lett. (2002)
- Asymmetric deactivation of racemic BINAP-Ru(II) catalysts through complete enantiomer discrimination by dimethylbinaphthylamine: highly enantioselective hydrogenation of olefin and beta-keto ester. Mikami, K., Yusa, Y., Korenaga, T. Org. Lett. (2002)
- Palladium-catalyzed isobenzofuran generation under neutral conditions via oxidative addition to lactol methyl ether. Mikami, K., Ohmura, H. Org. Lett. (2002)
- "Asymmetric" catalysis by lanthanide complexes. Mikami, K., Terada, M., Matsuzawa, H. Angew. Chem. Int. Ed. Engl. (2002)
- One-pot synthesis of tropinone by tandem (domino) ene-type reactions of acetone silyl enol ethers. Mikami, K., Ohmura, H. Chem. Commun. (Camb.) (2002)
- Asymmetric activation of chiral alkoxyzinc catalysts by chiral nitrogen activators for dialkylzinc addition to aldehydes: super high-throughput screening of combinatorial libraries of chiral ligands and activators by HPLC-CD/UV and HPLC-OR/RIU systems. Mikami, K., Angelaud, R., Ding, K., Ishii, A., Tanaka, A., Sawada, N., Kudo, K., Senda, M. Chemistry (2001)
- Asymmetric catalytic ene-cyclization approach to 2-fluoro-19-nor-1,25-dihydroxyvitamin D(3) A-ring analog with significant transactivation activity. Mikami, K., Ohba, S., Ohmura, H., Kubodera, N., Nakagawa, K., Okano, T. Chirality (2001)
- General synthetic route to chiral flexible biphenylphosphine ligands: the use of a chiral additive enables the preparation and observation of metal complexes incorporating the enantiopure form. Mikami, K., Aikawa, K., Korenaga, T. Org. Lett. (2001)
- Tetranuclear titanium 7,7'-modified binaphtholate cluster as a novel chiral Lewis acid catalyst. Mikami, K., Ueki, M., Matsumoto, Y., Terada, M. Chirality (2001)
- Enantiomer-selective activation of racemic catalysts. Mikami, K., Terada, M., Korenaga, T., Matsumoto, Y., Matsukawa, S. Acc. Chem. Res. (2000)
- Asymmetric imine-ene reactions: diastereofacial selective reactions with chiral glyoxylate-derived alpha-imino esters and asymmetric catalysis of enantiofacial selective reactions with prochiral alpha-imino esters. Mikami, K., Yajima, T., Kaneko, M. Amino. Acids (1998)
