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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

Robert D. Bach

Department of Chemistry and Biochemistry

University of Delaware


Delaware 19716

United States


Name/email consistency: high



  • Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States. 2001 - 2012


  1. The role of acid catalysis in the Baeyer-Villiger reaction. A theoretical study. Bach, R.D. J. Org. Chem. (2012) [Pubmed]
  2. Transient inverted metastable iron hydroperoxides in fenton chemistry. A nonenzymatic model for cytochrome p450 hydroxylation. Bach, R.D., Dmitrenko, O. J. Org. Chem. (2010) [Pubmed]
  3. The rate-limiting step in P450 hydroxylation of hydrocarbons a direct comparison of the "somersault" versus the "consensus" mechanism involving compound I. Bach, R.D. J. Phys. Chem. A (2010) [Pubmed]
  4. Ring strain energy in the cyclooctyl system. The effect of strain energy on [3 + 2] cycloaddition reactions with azides. Bach, R.D. J. Am. Chem. Soc. (2009) [Pubmed]
  5. Mechanism of thiolate-disulfide interchange reactions in biochemistry. Bach, R.D., Dmitrenko, O., Thorpe, C. J. Org. Chem. (2008) [Pubmed]
  6. The "somersault" mechanism for the p-450 hydroxylation of hydrocarbons. The intervention of transient inverted metastable hydroperoxides. Bach, R.D., Dmitrenko, O. J. Am. Chem. Soc. (2006) [Pubmed]
  7. The effect of carbonyl substitution on the strain energy of small ring compounds and their six-member ring reference compounds. Bach, R.D., Dmitrenko, O. J. Am. Chem. Soc. (2006) [Pubmed]
  8. Strain energy of small ring hydrocarbons. Influence of C-h bond dissociation energies. Bach, R.D., Dmitrenko, O. J. Am. Chem. Soc. (2004) [Pubmed]
  9. Relative reactivity of peracids versus dioxiranes (DMDO and TFDO) in the epoxidation of alkenes. A combined experimental and theoretical analysis. Bach, R.D., Dmitrenko, O., Adam, W., Schambony, S. J. Am. Chem. Soc. (2003) [Pubmed]
  10. Theoretical analysis of peroxynitrous acid: characterization of its elusive biradicaloid (HO...ONO) singlet states. Bach, R.D., Dmitrenko, O., Estévez, C.M. J. Am. Chem. Soc. (2003) [Pubmed]
  11. The effect of substitutents on the strain energies of small ring compounds. Bach, R.D., Dmitrenko, O. J. Org. Chem. (2002) [Pubmed]
  12. Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane. Bach, R.D., Dmitrenko, O. J. Org. Chem. (2002) [Pubmed]
  13. A theoretical study of the effect of a tetraalkylammonium counterion on the hydrogen bond strength in Z-hydrogen maleate. Bach, R.D., Dmitrenko, O., Glukhovtsev, M.N. J. Am. Chem. Soc. (2001) [Pubmed]
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