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Chemical Compound Review:

dioxoplatinum dioxoplatinum

Synonyms: PtO2, Adams Catalyst, Platinic oxide, ACMC-1AKY4, ANW-19307, ...

Jiang, H. et al., Watson, A.D. et al.

Watson, Subbanagounder, Welsbie, Faull, Navab, Jung, Fogelman, Berliner,

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High impact information on dioxoplatinum

Hydrogenation of the extracted 5,6-erythro-DHET with platinum(IV) oxide/hydrogen resulted in an increase of the molecular mass by 6 daltons and the same retention time shift as an authentic standard in gas chromatography, suggesting the existence of three olefins as well as the 5,6-erythro-dihydroxyl structure in the metabolite [1].

Biological context of dioxoplatinum

Hydrogenation with platinum(IV) oxide/hydrogen suggested a cyclic moiety, and reduction with sodium borohydride suggested two reducible oxygen-containing groups in the molecule [2].

References

Identification of 5,6-trans-epoxyeicosatrienoic acid in the phospholipids of red blood cells. Jiang, H., McGiff, J.C., Quilley, J., Sacerdoti, D., Reddy, L.M., Falck, J.R., Zhang, F., Lerea, K.M., Wong, P.Y. J. Biol. Chem. (2004) [Pubmed]
Structural identification of a novel pro-inflammatory epoxyisoprostane phospholipid in mildly oxidized low density lipoprotein. Watson, A.D., Subbanagounder, G., Welsbie, D.S., Faull, K.F., Navab, M., Jung, M.E., Fogelman, A.M., Berliner, J.A. J. Biol. Chem. (1999) [Pubmed]

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