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 Shi,  Xu,  
 

VO(acac)(2)-catalyzed oxidative coupling reactions of phosphonium salts.

A novel eco-safer protocol for the preparation of symmetric or asymmetric olefins directly from phosphonium salts under oxygen atmosphere in the presence of VO(acac)(2) (1.0 mol%) was developed.[1]

References

  1. VO(acac)(2)-catalyzed oxidative coupling reactions of phosphonium salts. Shi, M., Xu, B. J. Org. Chem. (2002) [Pubmed]
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