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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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 Itoh,  
 

The lowest excited triplet (T1) energies of p-methoxybenzaldehyde and p-cyanobenzaldehyde vapors estimated from the temperature dependence of the T2(n, pi*) phosphorescence and the S1(n, pi*) fluorescence spectra.

Invisible energy levels of the T1(pi, pi*) state of p-methoxybenzaldehyde (anisaldehyde) and p-cyanobenzaldehyde vapors have been estimated through the temperature dependence of the T2(n, pi*) --> S0 phosphorescence and the S1(n, pi*) --> S0 delayed fluorescence spectra. It is shown that the T1(pi, pi*) levels are located at 900 +/- 100 and 300 +/- 100 cm(-1) below the T2(n, pi*) levels, respectively, for p-methoxybenzaldehyde and p-cyanobenzaldehyde vapors. The estimated T1 energy levels are in good agreement with the phosphorescence origins in rigid glass at 77 K.[1]

References

  1. The lowest excited triplet (T1) energies of p-methoxybenzaldehyde and p-cyanobenzaldehyde vapors estimated from the temperature dependence of the T2(n, pi*) phosphorescence and the S1(n, pi*) fluorescence spectra. Itoh, T. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. (2003) [Pubmed]
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