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Nakamura, Y. et al.

Systematic enantiomeric separation of [60]fullerene bisadducts possessing an inherent chiral addition pattern.

The optical resolution of trans-2 and trans-3 [60]fullerene bisadducts with an inherent chiral addition pattern, modified by Bingel reaction, cycloaddition by benzyne, Prato reaction, and cycloaddition by o-quinodimethane, was systematically investigated by using chiral HPLC columns (Chiralcel OD and Chiralpak AD). The chiroptical properties of enantiomers separated were also examined.[1]

References

Systematic enantiomeric separation of [60]fullerene bisadducts possessing an inherent chiral addition pattern. Nakamura, Y., O-kawa, K., Nishimura, T., Yashima, E., Nishimura, J. J. Org. Chem. (2003) [Pubmed]

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