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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 

Effect on pKa of metal-bound water molecules in lanthanide ion-induced cyclen "cavities".

[reaction: see text] The macrocyclic cyclen conjugates 1-4 were synthesized with the aim of forming lanthanide ion-based macrocyclic conjugates possessing deep cavities, formed upon complexation to various lanthanide ions. These complexes all possess metal-bound water molecules, where the pK(a) of the water molecules depends on the nature of the cavity.[1]

References

  1. Effect on pKa of metal-bound water molecules in lanthanide ion-induced cyclen "cavities". Gunnlaugsson, T., Brougham, D.F., Fanning, A.M., Nieuwenhuyzen, M., O'brien, J.E., Viguier, R. Org. Lett. (2004) [Pubmed]
 
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