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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Intramolecular photoaddition of vinylogous amides with allenes: a novel approach to the synthesis of pyrroles.

Irradiation of vinylogous amide or imide 5 (R = H, alkyl, or Ac) leads to the selective formation of either crossed photoadduct 7 (R = Ac) or parallel photoadduct 8 (R = H or alkyl) as a function of the nature of the group R. The latter result leads to a novel approach to the synthesis of pyrroles, that is, 8'.[1]

References

  1. Intramolecular photoaddition of vinylogous amides with allenes: a novel approach to the synthesis of pyrroles. Winkler, J.D., Ragains, J.R. Org. Lett. (2006) [Pubmed]
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