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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Chemical Compound Review: 

Formimidol     N-methanoylmethanamide

Synonyms: Diformamide, Diformylamine, Iminoaldehyde, dicarboximides, CHEBI:35356, ...
 
 
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Disease relevance of N-methanoylmethanamide

  • The -CO(2)Et arms in 2,6-diformamido-1,3-diethoxycarbonylazulene effectively suppress the rate of dehydration of its 2-NHCHO end relative to that of the 6-NHCHO end leading to practically exclusive formation of 6-isocyano-2-formamido-1,3-diethoxycarbonylazulene upon treatment of the above diformamide with an equimolar amount of POCl(3) [1].

References

  1. The 2,6-diisocyanoazulene motif: synthesis and efficient mono- and heterobimetallic complexation with controlled orientation of the azulenic dipole. Holovics, T.C., Robinson, R.E., Weintrob, E.C., Toriyama, M., Lushington, G.H., Barybin, M.V. J. Am. Chem. Soc. (2006) [Pubmed]
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