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Chemical Compound Review:

sJPHADILuP@ 2-chlorobutane

Synonyms: CHEMBL346529, CCRIS 9391, C28898_ALDRICH, AG-H-16221, ACMC-209pfl, ...

Wiberg, K.B. et al.

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Disease relevance of UN1127

The temperature dependence of the specific rotations for 2-methylbutyronitrile and for 2-chlorobutane was studied to give experimental information about the effect of the torsion angle on the specific rotation [1].

High impact information on UN1127

The specific rotations derived from the study of 2-chlorobutane are similar to those previously obtained for 3-chloro-1-butene, indicating that the double bond does not have a large effect on the optical rotations, but it did lead to a large difference between calculated and observed specific rotations [1].

References

Conformational effects on optical rotation. 2-Substituted butanes. Wiberg, K.B., Wang, Y.G., Vaccaro, P.H., Cheeseman, J.R., Luderer, M.R. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. (2005) [Pubmed]

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