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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 
 
 

Electrooxidation mechanism of biogenic amines at amine oxidase modified graphite electrode.

Amine oxidase ( AO, EC. 1.4.3.6) was previously shown to be a very efficient biological recognition element of amperometric biosensors for monitoring biogenic amines. The enzyme was effectively working in both mono- and bienzyme electrode designs, based on either a direct or a mediated electron-transfer pathway. This work focuses on the elucidation of the electron-transfer mechanism of the monoenzymatic unmediated AO-modified biosensor. The observed unmediated catalytic currents were assumed to be caused by (i) a direct electron-transfer process, (ii) the electrooxidation of the formed product, or (iii) their combination. Experiments supporting these assumptions are discussed in detail.[1]

References

  1. Electrooxidation mechanism of biogenic amines at amine oxidase modified graphite electrode. Niculescu, M., Ruzgas, T., Nistor, C., Frébort, I., Sebela, M., Pec, P., Csöregi, E. Anal. Chem. (2000) [Pubmed]
 
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