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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Ferromagnetism in a dinuclear nickel(II) complex containing triethylenetetramine and tricyanomethanide.

Triethylenetetramine (L(4)) was used as a tetradentate blocking ligand that, after complexation with Ni(II), leaves two sites ready for ligation with tricyanomethanide. The formed binuclear complex [L(4)Ni(NCC(CN)CN)(2)NiL(4)](ClO(4))(2) exhibits a ferromagnetic coupling with J/hc = +0.15 cm(-1) and g(Ni) = 2.126; below 16 K, a ferromagnetic ordering is evidenced by ac magnetic susceptibility (both in-phase and out-of-phase), magnetization, field-cooled magnetization, and zero-field-cooled magnetization measurements.[1]

References

  1. Ferromagnetism in a dinuclear nickel(II) complex containing triethylenetetramine and tricyanomethanide. Boca, R., Gembický, M., Herchel, R., Haase, W., Jäger, L., Wagner, C., Ehrenberg, H., Fuess, H. Inorganic chemistry. (2003) [Pubmed]
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