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 Li,  Ma,  
 

A novel formal total synthesis of cephalotaxine.

A formal total synthesis of cephalotaxine (CET), the parent structure of antileukemia Cephalotaxus alkaloids, was achieved through a novel synthesis of the pentacyclic amino enone 4 by a rapid annulation of readily available beta-(3,4-methylenedioxy)phenethylamine (2), delta-valerolactone, and bromoacetone.[1]

References

  1. A novel formal total synthesis of cephalotaxine. Li, W.D., Ma, B.C. J. Org. Chem. (2005) [Pubmed]
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