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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Stereodifferentiation in the formation and decay of the encounter complex in bimolecular electron transfer with photoactivated acceptors.

Experimental evidence has been obtained for the involvement of encounter complexes between both enantiomers of a pi,pi* triplet excited ketone and a chiral phenol or indole. Determination of the pre-equilibrium constants (K(EC)) and the intrinsic decay rate constants (k(d)) indicates a significant stereodifferentiation in both steps of the quenching process.[1]

References

  1. Stereodifferentiation in the formation and decay of the encounter complex in bimolecular electron transfer with photoactivated acceptors. Pérez-Prieto, J., Galian, R.E., Morant-Miñana, M.C., Miranda, M.A. Chem. Commun. (Camb.) (2005) [Pubmed]
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