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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Synthesis and structural characterization of the first metal organic thallium antimonide.

The first metal organic thallium antimonide, the heterocycle [Me(2)TlSb(SiMe(3))(2)](3), was synthesized by reaction of [Me(2)AlSb(SiMe(3))(2)](3) with the Lewis acid-base adduct dmap-TlMe(3) (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle [Me(2)TlBi(SiMe(3))(2)](3) couldn't be isolated due to its limited thermal stability in solution.[1]

References

  1. Synthesis and structural characterization of the first metal organic thallium antimonide. Schulz, S., Thomas, F., Nieger, M. Chem. Commun. (Camb.) (2006) [Pubmed]
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