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Ni(II)(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA.

A simple Ni(II)(TPA) complex [ TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO(+) (nickel-oxo) type active oxygen species is suggested.[1]

References

  1. Ni(II)(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA. Nagataki, T., Tachi, Y., Itoh, S. Chem. Commun. (Camb.) (2006) [Pubmed]
 
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