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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)

Inorganic-organic hybrid membranes with anhydrous proton conduction prepared from 3-aminopropyltriethoxysilane and sulfuric Acid by the sol-gel method.

Inorganic-organic hybrid membranes with anhydrous proton conduction were prepared from 3-aminopropyltriethoxysilane and H2SO4 by the sol-gel method. The membrane has a unique structure: a hexagonal phase formed by the stacking of rodlike polysiloxanes with ion complexes of ammonium groups and HSO4- extruded outside. The membranes showed high conductivity of 2 x 10-3 S cm-1 at 200 degrees C under dry atmosphere. In the membrane, protons probably migrate through the outside of the rodlike polysiloxanes along hydrogen-bond chains formed among HSO4- anions.[1]


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