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Toward less dependence on platinum group metal catalysts: the merits of utilizing tin.

Minute stoichiometric bimetallic clusters rich in tin (PtSn 2, RhSn 2, and RuSn 2) are powerful selective hydrogenation catalysts: these "molecular metallic" entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.[1]

References

  1. Toward less dependence on platinum group metal catalysts: the merits of utilizing tin. Adams, R.D., Blom, D.A., Captain, B., Raja, R., Thomas, J.M., Trufan, E. Langmuir (2008) [Pubmed]
 
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