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Chemical Compound Review: 

Germane     germane

Synonyms: Monogermane, GeH4, ACMC-1BMG5, CHEBI:30443, HSDB 7911, ...
 
 
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High impact information on Germanium tetrahydride

  • The reactivity of diphenylgermylene (Ph2Ge) with several classes of germylene scavengers has been studied in hexane solution at 23 degrees C by laser flash photolysis of 3,4-dimethyl-1,1-diphenyl-1-germacyclopent-3-ene (1a), a clean and highly efficient precursor to the germylene and its dimer, tetraphenyldigermene (2a) [1].
  • Intermolecular C-H insertions and cyclization reactions involving a stable germylene [2].

References

  1. Di- and trivalent organogermanium reactive intermediates. Kinetics and mechanisms of some reactions of diphenylgermylene and tetraphenyldigermene in solution. Leigh, W.J., Harrington, C.R. J. Am. Chem. Soc. (2005) [Pubmed]
  2. Intermolecular C-H insertions and cyclization reactions involving a stable germylene. Miller, K.A., Watson, T.W., Bender, J.E., Banaszak Holl, M.M., Kampf, J.W. J. Am. Chem. Soc. (2001) [Pubmed]
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