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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Stereoselective synthesis of the optically active samin type of lignan from L-glutamic acid.

The optically active samin type of lignan, (1R,2S,5R, 6S)-6-(2-methoxy-4,5-methylenedioxyphenyl)-3,7-dioxabicyclo[3.3.0]octan-2-ol, was stereoselectively synthesized from L-glutamic acid via (2R,3R)-2-[(1S and R)1-[(tert - butyldimethylsilyl)oxyl-1-(2-methoxy-4,5methylenedioxyphenyl)methyl]-3-[(tert- butyldiphenylsilyl)oxylmethyl-1,4-butanediol.[1]

References

  1. Stereoselective synthesis of the optically active samin type of lignan from L-glutamic acid. Yamauchi, S., Yamamoto, N., Kinoshita, Y. Biosci. Biotechnol. Biochem. (2000) [Pubmed]
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