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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Hexafluorobenzene photochemistry: wellspring of fluorocarbon structures.

Ultraviolet irradiation of hexafluorobenzene in the vapor phase gives exclusively its Dewar valence isomer, from which a wealth of highly fluorinated compounds has been derived. Photoexcited in solution, hexafluorobenzene is capable of cycloaddition with a variety of unsaturated molecules. Like the Dewar benzene, resulting adducts have served as intermediates en route to many new fluorocarbons and fluorocarbon derivatives.[1]

References

  1. Hexafluorobenzene photochemistry: wellspring of fluorocarbon structures. Lemal, D.M. Acc. Chem. Res. (2001) [Pubmed]
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