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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 
 
 

Two crystal polymorphs of a flavonoid from Melicope ellyrana.

The crystal structure determinations of two crystalline components of the hexane extract of the fruit of the indigenous Australian tree Melicope ellyrana have shown them to be polymorphs of the same compound, namely the flavonoid 4',5-dihydroxy-3,3',8-trimethoxy-7-(3-methylbut-2-enyloxy)flavone [systematic name: 5-hydroxy-2-(4-hydroxy-3-methoxyphenyl)-3,8-dimethoxy-7-(3-methylbut-2-enyloxy)-4H-1-benzopyran-4-one], C(23)H(24)O(8). The two polymorphs, one monoclinic (polymorph A) and the other triclinic (polymorph B), show significant conformational differences, particularly in the enyloxy side chain, while only one (polymorph A) shows intermolecular hydrogen bonding.[1]

References

  1. Two crystal polymorphs of a flavonoid from Melicope ellyrana. Smith, G., Bartley, J.P., Wang, E., Bott, R.C. Acta crystallographica. Section C, Crystal structure communications. (2001) [Pubmed]
 
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