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Keck, G.E. et al.

Keck, Truong,

Directed reduction of beta-amino ketones to syn or anti 1,3-amino alcohol derivatives.

[reaction: see text] The reduction of beta-amino ketones with samarium(II) iodide has been investigated. Either the syn or anti 1,3-amino alcohols can be obtained as the major product due to a divergence in selectivity with different N-protecting groups.[1]

References

Directed reduction of beta-amino ketones to syn or anti 1,3-amino alcohol derivatives. Keck, G.E., Truong, A.P. Org. Lett. (2002) [Pubmed]

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