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Gunnlaugsson, T. et al.

Gunnlaugsson, Harte, Leonard, Nieuwenhuyzen,

Delayed lanthanide luminescence sensing of aromatic carboxylates using heptadentate triamide Tb(III) cyclen complexes: the recognition of salicylic acid in water.

The coordinately unsaturated terbium complexes Tb.1 and Tb.2 possess two labile metal-bound water molecules that can be displaced upon metal chelation to aromatic carboxylic anions such as salicylic acid in water, which gives rise to large enhancements in the Tb(III) luminescence.[1]

References

Delayed lanthanide luminescence sensing of aromatic carboxylates using heptadentate triamide Tb(III) cyclen complexes: the recognition of salicylic acid in water. Gunnlaugsson, T., Harte, A.J., Leonard, J.P., Nieuwenhuyzen, M. Chem. Commun. (Camb.) (2002) [Pubmed]

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