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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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On the complex formation equilibria between dioxouranium(VI) and sulfate ions.

The complexation equilibria between UO2(2+) and SO4(2-) ions have been studied at 25 degrees C in the ionic medium 3 M NaClO4 by potentiometry, by spectrophotometry and by solubility measurements of UO2(IO3)2. The potentiometric investigation was carried out with the Hg-Hg2SO4(s)-SO4(2-) half-cell and glass electrode in the sulfate concentration range 0.005 to 0.07 M. The optical absorbances in the UV-visible region and the solubility data cover the ligand concentration range 0.005 to 0.3 M. The data could be explained by assuming the complexes and equilibrium constants [Table: see text]. The constants in the infinite dilution reference state, log beta1o = 3.08 +/- 0.15 and log beta2o = 4.28 +/- 0.15, estimated by assuming the validity of the specific interaction theory, are practically coincident with literature data.[1]

References

  1. On the complex formation equilibria between dioxouranium(VI) and sulfate ions. Ciavatta, L., De Tommaso, G., Iuliano, M. Annali di chimica. (2003) [Pubmed]
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