Strengthening effect of aluminum fluoride added to resin composites based on polyacid-containing polymer.
OBJECTIVES: The study investigates the possible strengthening effect of aluminum ions liberated during long-time water storage of experimental resin composites containing a polymer with carboxylic acid groups. METHODS: The organic part of the resin composites was formed by photopolymerization of methacrylate monomers. The monomer mixture was composed of UEDMA, HEMA or TEGDMA, and 0-40 mol% HEMAN (the adduct of HEMA and maleic anhydride). The filler part of the resin composites consisted of a conventional silanated glass filler and 1 or 5 wt% of AlF3 x 3H2O. The rupture strength and bending modulus were measured without water storage and after 1 month, 1 year, and 3 years of water storage at 37 degrees C of the resin composite. RESULTS: The experimental composites that had been stored in water had lower rupture strength and modulus than the composites that were tested without water storage. Specimens containing 30 or 40 mol% HEMAN increased in strength, and specimens containing 20, 30, or 40 mol% HEMAN increased in modulus during the period of water storage. Depending on composition, values for strength and modulus obtained after 3 years of water storage was up to 50% higher than the values obtained after 1 month. SIGNIFICANCE: The strengthening effect of aluminum fluoride may be interpreted as the result of increased crosslinking by aluminum ions and carboxylate groups. The results may serve as a basis for the improvement of the mechanical properties of polyacid-modified resin composites.[1]References
- Strengthening effect of aluminum fluoride added to resin composites based on polyacid-containing polymer. Asmussen, E., Peutzfeldt, A. Dental materials : official publication of the Academy of Dental Materials. (2003) [Pubmed]
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