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Adsorption and surface rheology of n-dodecanol at the water/air interface.

Adsorption layers of n-dodecanol at the water/air interface show phase transitions at low temperatures [Vollhardt, Fainerman, Emrich, J. Phys. Chem. B 104 (2000) 8536]. Using a drop shape technique it is shown that the dilational elasticity disappears in the coexistence region of the adsorption layer. The relaxation time between the condensed and liquid-like surface states is in the sub-second time range.[1]


  1. Adsorption and surface rheology of n-dodecanol at the water/air interface. Ferrari, M., Ravera, F., Liggieri, L., Motschmann, H., Yi, Z., Krägel, J., Miller, R. Journal of colloid and interface science. (2004) [Pubmed]
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