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Diels-Alder reaction between indoles and cyclohexadienes photocatalyzed by pi,pi aromatic ketones.

[structure: see text] Diels-Alder reactions between indoles and cyclohexadienes can be photocatalyzed by benzoylthiophenes. Both experimental and theoretical studies show that the reactions occur through ternary excited triplet state complexes (triplet triplexes).[1]

References

  1. Diels-Alder reaction between indoles and cyclohexadienes photocatalyzed by pi,pi aromatic ketones. Pérez-Prieto, J., Stiriba, S.E., González-Béjar, M., Domingo, L.R., Miranda, M.A. Org. Lett. (2004) [Pubmed]
 
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