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Hoffmann, R. A wiki for the life sciences where authorship matters. Nature Genetics (2008)
 

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Triethylsilane-indium(III) chloride system as a radical reagent.

[reaction: see text] A novel generation method of indium hydride (Cl(2)InH) was found by the transmetalation of InCl(3) with Et(3)SiH. In the intramolecular cyclization of enynes, the previously reported system (NaBH(4)-InCl(3)) has a problem of side reactions with the coexistent borane. In contrast, the problem was solved by the presented system, which affords effective hydroindation of alkynes.[1]

References

  1. Triethylsilane-indium(III) chloride system as a radical reagent. Hayashi, N., Shibata, I., Baba, A. Org. Lett. (2004) [Pubmed]
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