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Gaudichanolides A and B, clerodane diterpenes from Baccharis gaudichaudiana.

Two new clerodane diterpenoids, gaudichanolides A (1) and B (2), were isolated from the dried twigs of Baccharis gaudichaudiana, together with 7-oxo-16,19-dihydroxy-3,4-dehydroclerodan-15,20-diacid dilactone, spathulenol, 4,10-aromadendranediol, kobusone, trans-cosanyl ferulate, and defuscin. The structures and relative stereochemistry of 1 and 2 were elucidated by detailed 2D NMR spectroscopic experiments, and the absolute stereochemistry of 1 was determined by X-ray crystallographic analysis.[1]

References

  1. Gaudichanolides A and B, clerodane diterpenes from Baccharis gaudichaudiana. Hayashi, K., Kanamori, T., Yamazoe, A., Yamada, M., Nozaki, H. J. Nat. Prod. (2005) [Pubmed]
 
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